10+ most rarest and expensive Mega Brave card list to hunt

Mega Brave card list is one of the most exciting topics for Pokémon TCG collectors in 2025, bringing together rare chase cards, nostalgic Mega Evolutions, and stunning Trainer artworks. This set has quickly captured global attention, not only for its beautiful designs but also for the impressive market value of its top pulls. Whether you’re a long-time Pokémon fan or a new collector exploring Japanese sets, Mega Brave offers both investment potential and collecting joy. 

Keep reading this guide to discover the rarest and most expensive cards you should be hunting and don’t forget to check out more exclusive updates at Japan Figure for your next must-have addition.

1. Overview to Pokemon Mega Brave set

The Mega Brave card list marks an exciting turning point in the Pokémon TCG, ushering in the brand-new Mega Evolution era. Released on August 1, 2025, Mega Brave launched alongside Mega Symphonia as the dual first main expansion sets of this new generation. For international fans, these sets are the Japanese counterparts of the upcoming English release, Mega Evolution (Base Set), scheduled for September 26, 2025.

This release officially closes the chapter on Scarlet & Violet and signals the start of something fresh. Tied to the upcoming console game Legends: Z-A, Mega Brave reintroduces powerful Mega Evolutions such as Mega Lucario, Mega Venusaur, Mega Absol, Mega Mawile, and Mega Camerupt. Collectors and players alike are thrilled to see these classic favorites return with updated mechanics and dazzling new card designs.

When Scarlet & Violet was nearing its end, speculation grew that Art Rare (AR) and Special Art Rare (SAR) cards might undergo big changes. However, Mega Brave confirms that both rarities will remain part of the game, though with some exciting new twists.

Here are some of the standout updates introduced in the Mega Brave expansion:

• A new gold card rarity called Mega Ultra Rare (MUR), featuring original artwork rather than recolored versions of existing full arts.
• Full-art Trainer cards are now standard in the set, not just limited to gold cards.
• Full-art cards sport a shimmery, glittering finish, enhancing their collectible appeal.
• For competitive play, Mega Evolutions now evolve from their final pre-evolution stage (e.g., Mega Venusaur ex evolves from Ivysaur), and instead of ending a player’s turn upon evolution, these cards now give up three Prize Cards when knocked out.

2. 10+ most rarest and expensive Mega Brave card list to hunt

All these updates make Mega Brave one of the most groundbreaking sets in recent memory, combining nostalgia, gameplay depth, and collector value. Some collectors have even compared this excitement to other standout modern sets like Inferno X Pokemon, which also introduced powerful new themes and chase cards.

Curious which cards stand out the most? Let’s dive into the 10+ most rare and expensive Mega Brave card list to hunt.

1. Mega Lucario Ex #92 ~ $379.98 
2. Lillie's Determination #91 ~ $250.00 
3. Mega Lucario ex #88 ~ $76.84 
4. Mega Venusaur ex #87 ~ $65.41 
5. Lillie's Determination #86 ~ $43.77 
6. Mega Absol Ex #89 ~ $33.55 
7. Mega Lucario Ex #78 ~ $15.00 
8. Bulbasaur #64 ~ $12.45 
9. Mega Venusaur Ex #76 ~ $11.75 
10. Lt. Surge's Deal #90 ~ $10.88 

2.1 Mega Lucario Ex #92 ~ $379.98 

Mega Lucario ex #92 is considered the crown jewel of Mega Brave. With its gold-etched Mega Ultra Rare finish, this card combines striking visuals with extreme scarcity. As with popular dual-set releases like MEGA Dream ex and Abyss Eye, this premium design has fueled massive collector demand.

• Rarity / Spec: MUR (Mega Ultra Rare) – gold-etched unique artwork
• Illustrator: 5ban Graphics
• Release: August 1, 2025 (Mega Brave, Secret Rare slot)
• Pull Rate: Extremely low – among the rarest pulls in the entire set
• Price Range: ~$310–$639 (graded), around ~$379.98 ungraded

2.2 Lillie's Determination #91 ~ $250.00 

Trainer cards often rank among the most expensive collectibles, and Lillie’s Determination #91 is no exception. This SAR artwork attracts dedicated fans, similar to the way niche-themed sets like Ninja Spinner Pokemon TCG appeal to collectors who enjoy unique character-driven designs.

• Rarity / Spec: SAR (Special Art Rare)
• Illustrator: satoma
• Release: August 1, 2025 (Mega Brave, Secret Rare pool)
• Pull Rate: Very low – Special Art Rares are among the hardest to pull
• Price Range: ~$250 ungraded, PSA 10 copies can exceed $1,000+

2.3 Mega Lucario ex #88 ~ $76.84 

This version of Mega Lucario ex is far more affordable than the #92 MUR, yet still highly sought-after. With its alternate artwork and status as a Secret Rare, it provides a balance between rarity and accessibility. Collectors see this as a smart entry point for owning a Mega Lucario without paying the top-tier premium.

• Rarity / Spec: SAR / Secret Rare (alternate art version)
• Illustrator: Alternate artwork (varies by edition)
• Release: August 1, 2025 (Mega Brave, Secret Rare pool)
• Pull Rate: More attainable than MUR, but still lower than standard SRs
• Price Range: ~$70–$90 depending on condition

2.4 Mega Venusaur ex #87 ~ $65.41 

Mega Venusaur ex #87 highlights the strength of Grass-type Mega Evolutions in the Mega Brave set. Its full-art design makes it stand out among collectors who appreciate classic Kanto Pokémon. While not as pricey as Mega Lucario, it’s still a respectable chase card that bridges nostalgia with the new Mega Brave mechanics.

• Rarity / Spec: SR / Special Art Rare (full-art style)
• Illustrator: Alternate art illustrator (varies by edition)
• Release: August 1, 2025 (Mega Brave, Secret Rare slot)
• Pull Rate: Rare but more accessible than MUR or top SARs
• Price Range: ~$55–$70 depending on condition

2.5 Lillie's Determination #86 ~ $43.77 

This is another variant of the beloved Trainer card Lillie’s Determination. While less expensive than the SAR version (#91), it still captures attention due to its detailed illustration and rarity. Collectors who want to complete the “Lillie lineup” in Mega Brave often add this card alongside the higher-tier chase.

• Rarity / Spec: AR / Special Art Trainer variant
• Illustrator: Variant illustrator (different from SAR #91)
• Release: August 1, 2025 (Mega Brave, Secret Rare / Art Rare pool)
• Pull Rate: Easier to find than #91, but still classed as a rare pull
• Price Range: ~$35–$50 depending on market demand

2.6 Mega Absol Ex #89 ~ $33.55 

Mega Absol ex #89 appeals to fans of Dark-type Pokémon with its sleek and edgy artwork. Though not the most expensive card in the set, it offers strong collector appeal thanks to Absol’s cult following. For many, it’s a mid-tier chase that adds variety and personality to a Mega Brave collection.

• Rarity / Spec: SR / Special Art Rare
• Illustrator: Full-art dark aesthetic
• Release: August 1, 2025 (Mega Brave, Secret Rare slot)
• Pull Rate: Rare but more accessible than Lucario or Venusaur variants
• Price Range: ~$30–$40

2.7 Mega Lucario Ex #78 ~ $15.00 

The Mega Lucario ex #78 is one of the more affordable chase cards in the set. It’s not as rare or prestigious as the gold MUR version, but it still allows collectors to own a Mega Lucario card without breaking the bank. This makes it especially popular with newer collectors or those looking to build a complete Mega Lucario line.

• Rarity / Spec: SR / lower-tier Secret Rare
• Illustrator: Standard full-art style
• Release: August 1, 2025 (Mega Brave, Secret Rare slot)
• Pull Rate: More common than high-tier chase cards
• Price Range: ~$12–$18

2.8 Bulbasaur #64 ~ $12.45 

Bulbasaur #64 adds a nostalgic touch to the Mega Brave lineup, appealing to collectors who love the original Kanto starters. While it doesn’t carry the same price tag as Mega Evolutions or Trainer SARs, its charm lies in its simplicity and popularity among fans. This makes it a low-cost but meaningful pick for set completion.

• Rarity / Spec: AR (Art Rare)
• Illustrator: Soft, playful illustration style
• Release: August 1, 2025 (Mega Brave, Art Rare pool)
• Pull Rate: Moderate – easier to obtain than SARs or MURs
• Price Range: ~$10–$15

2.9 Mega Venusaur Ex #76 ~ $11.75 

This version of Mega Venusaur ex is one of the more affordable Mega cards in the set. Unlike the pricier #87, this card is easier to find but still holds value for collectors who want a full Mega Venusaur line. It’s a great entry-level option for fans who prefer Grass-type Pokémon.

• Rarity / Spec: SR / lower-tier Secret Rare
• Illustrator: Standard full-art illustrator
• Release: August 1, 2025 (Mega Brave, Secret Rare slot)
• Pull Rate: Common compared to high-tier Secret Rares
• Price Range: ~$10–$14

2.10 Lt. Surge's Deal #90 ~ $10.88 

Trainer cards always hold a special place in Pokémon TCG, and Lt. Surge’s Deal #90 is no exception. Though it’s one of the cheapest chase cards in Mega Brave, it has unique artwork that appeals to Trainer card collectors. It rounds out the set as an accessible yet collectible pull.

• Rarity / Spec: SR / Trainer Rare
• Illustrator: Unique Trainer card artwork
• Release: August 1, 2025 (Mega Brave, Secret Rare slot)
• Pull Rate: Easier than Lillie’s Determination, moderate rarity
• Price Range: ~$9–$12

3. Pokemon Mega Brave and Mega Symphonia: Comparison guide

Both Mega Brave and Mega Symphonia are standout Pokémon TCG sets released in 2025, sparking massive interest among collectors worldwide. While they share certain similarities in style and structure, there are also key differences that influence which set is more worth hunting for.

If you’re a nostalgic fan who loves Mega Evolutions and trainer-focused cards, then Mega Brave is the better option to chase. Its lineup of Mega Lucario ex, Mega Venusaur ex, and Lillie’s Determination offers both affordability and prestige.

On the other hand, if you prefer artistic flair and higher-value chase cards, then Mega Symphonia edges ahead, thanks to its standout SARs like Mega Gardevoir ex.

For long-term investment, Mega Symphonia might hold stronger resale value, but for balance between cost, nostalgia, and collectability, Mega Brave remains a must-have set.

Exploring the Mega Brave card list reveals just how much excitement this set brings to collectors worldwide. From the powerhouse Mega Lucario ex to fan-favorite Trainer cards like Lillie’s Determination, Mega Brave offers a unique mix of nostalgia, artistry, and long-term value. Whether you’re chasing the rarest pulls or simply looking to complete your collection, this set proves to be one of the most rewarding releases of 2025.

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Rikuya Takamine

Rikuya Takamine has been writing about Japanese pop culture for over 7 years. With a background in Media and Communications and extensive experience covering major TCG releases and collectible figure launches, he delivers content that blends accuracy with excitement. His work has appeared on leading Japanese pop culture platforms, and he has contributed to respected magazines such as V Jump and Hobby Japan, both well-known in the fields of gaming, trading card games, and collectibles.

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